6533b7cefe1ef96bd1257121
RESEARCH PRODUCT
Calix[4]arene-functionalized naphthalene and perylene imide dyes.
Frank WürthnerChang-cheng YouMyroslav O. VysotskyKari RissanenVolker Böhmersubject
Molecular StructureChemistryOrganic ChemistryCrystal structureNuclear magnetic resonance spectroscopyNaphthalenesPhotochemistryImidesBiochemistryFluorescencechemistry.chemical_compoundPhenolsPolymer chemistryCalixareneMoleculePhysical and Theoretical ChemistryCalixarenesImideColoring AgentsPerylenePeryleneNaphthaleneFluorescent Dyesdescription
[reaction: see text] Calix[4]arenes bearing one, two, or four 1,8-naphthyl imide groups at the wide rim and bis-calix[4]arenes connected via perylene-bisimide dye spacers have been synthesized. The low-temperature NMR spectrum of the tetranaphthylimide suggests, in agreement with a crystal structure, a C2-symmetrical pinched cone conformation stabilized via face-to-face pi-pi interactions between opposite naphthylimide groups. UV-vis and fluorescence studies have been carried out for the perylene bis-calix[4]arene dyes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-07-26 | Organic letters |