6533b7cffe1ef96bd12584fb

RESEARCH PRODUCT

Touching the upper limit for ferromagnetic interactions in hetero-bridged dinuclear [Cu-2(II)] complexes using a novel N-5-dinucleating ligand bearing an endogenous monoatomic amido(R-NH-)-bridging group

Antonio J. MotaAlessandro PrescimonePetri SeppäläReijo SillanpääMikko M. HänninenEuan K. BrechinJesus E. Perea‐bucetaEnrique Colacio

subject

Monatomic gas/dk/atira/pure/subjectarea/asjc/2500/2508Bridging (networking)Chemistry(all)Stereochemistry/dk/atira/pure/subjectarea/asjc/2500/2505/dk/atira/pure/subjectarea/asjc/2500/2504/dk/atira/pure/subjectarea/asjc/2500/2506chemistry.chemical_elementCatalysisMaterials Chemistry/dk/atira/pure/subjectarea/asjc/2500/2503/dk/atira/pure/subjectarea/asjc/1600ta116COPPER(II) COMPLEXESMetals and AlloysCLUSTERGeneral ChemistryCopperSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyFerromagnetismchemistryCeramics and Composites/dk/atira/pure/subjectarea/asjc/1500/1503

description

A novel N-5-dinucleating ligand 4-amino-3,5-bis(bipyridine-2-yl)-1,2,4-triazole allows the preparation for the first time, and under mild conditions, of single and mixed amido(R-NH-)-bridged copper(II) complexes, the latter exhibiting very strong ferromagnetic coupling.

10.1039/c1cc16590ahttps://hdl.handle.net/20.500.11820/806eac39-8e33-4897-b7a7-4517190c3e3f