6533b7cffe1ef96bd1258589
RESEARCH PRODUCT
Tuning the photophysical properties of anti-B18H22: efficient intersystem crossing between excited singlet and triplet states in new 4,4'-(HS)2-anti-B18H20.
Drahomír HnykJosep M. OlivaPavel KubátIvana CísařováVicenta SauriJakub BraborecJonathan BouldManuela MerchánKamil LangMichael G. S. Londesboroughsubject
Inorganic Chemistrychemistry.chemical_compoundIntersystem crossingchemistryHydrideSinglet oxygenAb initioQuantum yieldDensity functional theoryPhysical and Theoretical ChemistrySpectroscopyPhotochemistryFluorescencedescription
The tuning of the photophysical properties of the highly fluorescent boron hydride cluster anti-B18H22 (1), by straightforward chemical substitution to produce 4,4'-(HS)2-anti-B18H20 (2), facilitates intersystem crossing from excited singlet states to a triplet manifold. This subsequently enhances O2((1)Δg) singlet oxygen production from a quantum yield of ΦΔ ∼ 0.008 in 1 to 0.59 in 2. This paper describes the synthesis and full structural characterization of the new compound 4,4'-(HS)2-anti-B18H20 (2) and uses UV-vis spectroscopy coupled with density functional theory (DFT) and ab initio computational studies to delineate and explain its photophysical properties.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-07-26 | Inorganic chemistry |