6533b7cffe1ef96bd125991f

RESEARCH PRODUCT

Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2'-bipyrimidine-bridged cobalt(II) framework.

Nadia MarinoTeresa F. MastropietroRobert P. DoyleGiovanni De MunnoDonatella ArmentanoMiguel JulveFrancesc Lloret

subject

Inorganic ChemistryCrystallographychemistry.chemical_compoundChemistryInorganic chemistryAntiferromagnetismchemistry.chemical_elementCobaltPyrophosphateSpin canting

description

The three-dimensional cobalt(ii) compound of formula {[Co(2)(P(2)O(7))(bpym)(2)].12H(2)O}(n), where the pyrophosphate and 2,2'-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with T(c) = 19 K.

yearjournalcountryeditionlanguage
2008-09-25Dalton transactions (Cambridge, England : 2003)
10.1039/b813097nhttps://pubmed.ncbi.nlm.nih.gov/18813367