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RESEARCH PRODUCT
Modelling the transport of carbonic acid anions through anion-exchange membranes
Victor NikonenkoGérald PourcellyK. A. LebedevJosé A. Manzanaressubject
Carbonic acidchemistry.chemical_classificationIon exchangeThermodynamic equilibriumGeneral Chemical EngineeringDiffusionBicarbonateInorganic chemistrySalt (chemistry)02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical scienceschemistry.chemical_compoundsymbols.namesakeMembranechemistryElectrochemistrysymbols[CHIM]Chemical SciencesNernst equation0210 nano-technologyComputingMilieux_MISCELLANEOUSdescription
Electrodiffusion of carbonate and bicarbonate anions through anion-exchange membranes (AEM) is described on the basis of the Nernst � /Planck equations taking into account coupled hydrolysis reactions in the external diffusion boundary layers (DBLs) and internal pore solution. The model supposes local electroneutrality as well as chemical and thermodynamic equilibrium. The transport is considered in three layers being an anion exchange membrane and two adjoining diffusion layers. A mechanism of
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-10-01 | Electrochimica Acta |