6533b7d0fe1ef96bd125a47b
RESEARCH PRODUCT
A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group
Maurici López-jordàMiguel Clemente-leónAlexandre AbhervéCarlos J. Gómez-garcíaEugenio Coronadosubject
010405 organic chemistryStereochemistryLigandSpin transition010402 general chemistry01 natural sciencesMedicinal chemistry3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundLinear networkBPP ligandchemistrySpin crossoverGroup (periodic table)PyridineCarboxylatedescription
Combining Fe(ii) with the carboxylate-functionalized 2,6-bis(pyrazol-1-yl)pyridine (bppCOOH) ligand results in the spin-crossover compound [Fe(bppCOOH)2](ClO4)2 which shows an abrupt spin transition with a T1/2 of ca. 380 K and a TLIESST of 60 K due to the presence of a hydrogen-bonded linear network of complexes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-05-09 | Dalton Transactions |