6533b7d0fe1ef96bd125a544

RESEARCH PRODUCT

Ellipsoid-shaped superparamagnetic nanoclusters through emulsion electrospinning.

Luciano F. BoeselRené M. RossiGiuseppino FortunatoAgathe CamerloSebastian UlrichGerhard JakobMarkus B. Bannwarth

subject

Microscopy Electron Scanning TransmissionMaterials scienceNanotechnologyPolyvinyl alcoholFerric CompoundsCatalysisNanoclusterschemistry.chemical_compoundMaterials ChemistryDissolutionchemistry.chemical_classificationMagnetic PhenomenaMetals and AlloysGeneral ChemistryPolymerOctanesElectrospinningSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsNanostructuresChemical engineeringchemistryNanofiberPolyvinyl AlcoholEmulsionCeramics and CompositesMicroscopy Electron ScanningEmulsionsSuperparamagnetism

description

Ellipsoid-shaped nanoclusters composed of single superparamagnetic nanoparticles can be generated by emulsion electrospinning. Stretching and subsequent solvent evaporation of iron oxide loaded emulsion droplets during the emulsion electrospinning process enables the creation of such structures embedded in polymer nanofibers. Dissolution of the polymer fibers yields an aqueous dispersion of the inorganic clusters which are the first example of ellipsoid-shaped superparamagnetic nanoclusters with a high saturation magnetization (∼47 emu g(-1)).

10.1039/c4cc10076jhttps://pubmed.ncbi.nlm.nih.gov/25646769