6533b7d0fe1ef96bd125aba7

RESEARCH PRODUCT

1H NMR spectra of Ph2SbX, PhSbX2, and Ph3SbX2 (XCl, Br, I); 121Sb Mössbauer spectra of PhSbX2 and crystal structure of Ph2SbI1

Michael DenkerHans Joachim BreunigKlaus H. EbertGiuseppe AlonzoW Offermann

subject

StereochemistryOrganic Chemistrychemistry.chemical_elementCrystal structureBiochemistrySpectral lineInorganic ChemistryCrystallographyAntimonychemistryMaterials ChemistryProton NMRMoleculeMossbauer spectraPhysical and Theoretical Chemistry

description

1H NMR spectroscopic data of Ph2SbX, PhSbX2, and Ph3SbX2 (XCl, Br, I) have been determined by iterative simulation. 121Sb Mossbauer spectra of PhSbX2 (XCl, Br, I) have been measured. The synthesis of Ph2SbI is achieved by reaction of Ph2SbCl with NaI in ethanol. The crystal structure of Ph2SbI consists of molecules with pyramidal C2SbI units.

yearjournalcountryeditionlanguage
1996-09-01Journal of Organometallic Chemistry
https://doi.org/10.1016/0022-328x(96)06286-9