6533b7d0fe1ef96bd125abbc
RESEARCH PRODUCT
Convenient Synthesis of 3-Cinnamoyl-2-styrylchromones: Reinvestigation of the Baker-Venkataraman Rearrangement
Gregor SchnakenburgOlivia NeumannOlga N. KataevaPia KönigsSiegfried R. WaldvogelSiegfried R. Waldvogelsubject
chemistry.chemical_compoundchemistryOne pot reactionOrganic ChemistryBaker–Venkataraman rearrangementMoleculeOrganic chemistrySequence (biology)Physical and Theoretical ChemistrySolubilityCombinatorial chemistryChemical synthesisAcetophenonedescription
An efficient and straightforward, one-pot sequence gives access to highly functionalized 3-cinnamoyl-2-styrylchromones in excellent yields. The low solubility of the target molecules allows convenient isolation. The formation of an α,α-dicinnamoylated acetophenone, as a consequence of a two-fold Baker-Venkataraman sequence, has to be anticipated.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-10-18 | European Journal of Organic Chemistry |