6533b7d0fe1ef96bd125abc5
RESEARCH PRODUCT
Dienediolates of unsaturated carboxylic acids in synthesis. Synthesis of cyclohexenones and polycyclic ketones by tandem Michael-Dieckmann decarboxylative annulation of unsaturated carboxylic acids.
Pablo GaviñaMaría José AurellRamon Mestressubject
chemistry.chemical_classificationAnnulationCarboxylic acidOrganic ChemistryBiochemistryCinnamic acidchemistry.chemical_compoundAlicyclic compoundchemistryCascade reactionDrug DiscoveryMichael reactionOrganic chemistryAliphatic compoundEnonedescription
Abstract Substituted 2-cyclohexenones 4 to 7 and hexaxydronaphthalenones and hexahydroindenones 13 to 18 are prepared by tandem Michael-Dieckmann addition of lithium dienediolates of acyclic and alicyclic unsaturated carboxylic acids to the lithium salts of the same or other unsaturated carboxylic acids.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1994-02-01 | Tetrahedron |