6533b7d0fe1ef96bd125ac0f

RESEARCH PRODUCT

FIRST EXAMPLES OF DISELENO TWEEZER-LIKE LIGANDS: SYNTHESIS, CHARACTERIZATION AND Pt(II) CYCLOMETALATION

Philippe MeunierR. LouisM. A. El AmiriN. PirioH. Ossor

subject

Inorganic ChemistryChemistryOrganic ChemistryMoleculechemistry.chemical_elementOrganic chemistryNuclear magnetic resonance spectroscopyPlatinumMass spectrometryBiochemistryCombinatorial chemistryCharacterization (materials science)

description

Abstract The synthesis of the first examples of diseleno tweezer-like molecules is described starting from diselenocyanobenzenic or pyridinic compounds and chloronaphthyl or anthryl derivatives. The new diselenides are characterized by mass spectrometry and multinuclear NMR spectroscopy. Starting from naphthyl derivatives, it was unambigously demonstrated for the first time their cyclometalation with Pt(II) to form metalloreceptors.

yearjournalcountryeditionlanguage
2000-01-01Phosphorus, Sulfur, and Silicon and the Related Elements
https://doi.org/10.1080/10426500008044989