6533b7d0fe1ef96bd125afac
RESEARCH PRODUCT
First synthesis of single-“strapped cyclam-porphyrins”
Bernard BoitrelRoger Guilardsubject
1h nmr spectroscopybiology010405 organic chemistryStereochemistryOrganic ChemistryNuclear magnetic resonance spectroscopy010402 general chemistryMass spectrometry[ CHIM ] Chemical Sciences01 natural sciencesBiochemistry0104 chemical scienceschemistry.chemical_compoundchemistry[CHIM] Chemical SciencesDrug DiscoveryCyclamProton NMRbiology.proteinLactam[CHIM]Chemical SciencesCytochrome c oxidaseComputingMilieux_MISCELLANEOUSCyclophanedescription
The first synthesis of strapped cyclam porphyrins is described ; these will be studied as dioxygen carriers as well as cytochrome C oxidase models. The original derivatives are characterized by mass spectrometry and 1H NMR spectroscopy. The cofacial conformation of the two different macrocycles is confirmed by 1H NMR data.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1994-05-01 | Tetrahedron Letters |