6533b7d0fe1ef96bd125b6de

RESEARCH PRODUCT

Zirconocene [Cp2Zr] synthon and benzynezirconocene complexes as tools in main group element chemistry

Stéphane BredeauAlain IgauNadine PirioPhilippe MeunierAleksandra SkowrońskaMaria ZablockaJean-pierre Majoral

subject

Inorganic ChemistrychemistryAntimonyMain group elementSynthonMaterials Chemistrychemistry.chemical_elementOrganic chemistryGermaniumPhysical and Theoretical ChemistryTinAryneSelenium

description

Abstract Interactions between zirconocene or benzyne zirconocene and unsaturated species incorporating main group elements lead to a variety of new metallaheterocycles. Efficient new methodologies of regiospecific syntheses of mono-, bi-, or tricyclic systems incorporating phosphorus, nitrogen, selenium, antimony, germanium or tin are reported.

https://doi.org/10.1016/s0010-8545(98)00165-9