Zirconocen–Benzyme-Mediated Intramolecular Coupling of Bis(alkynyl)phosphane: A Way to Mono- and Tricyclic 1,2-Dihydrophosphetes

Zirconocene [Cp2Zr] synthon and benzynezirconocene complexes as tools in main group element chemistry

Abstract Interactions between zirconocene or benzyne zirconocene and unsaturated species incorporating main group elements lead to a variety of new metallaheterocycles. Efficient new methodologies of regiospecific syntheses of mono-, bi-, or tricyclic systems incorporating phosphorus, nitrogen, selenium, antimony, germanium or tin are reported.

Intramolecular coupling of acetylenic groups of bis(alkynyl)phosphanes and silanes mediated by benzynezirconocene: a route to new mono- and tricyclic heterocycles

Benzo-zirconacyclohexadiene-phospha or silacyclobutene fused ring systems are easily prepared via a benzynezirconocene intermediate by means of thermolysis of Cp 2 ZrPh 2 in the presence of bis(alkynyl)phosphanes or silanes. These polyunsaturated systems are the source of a variety of new mono- or tricyclic heterocycles incorporating either one or two heteroatoms.

Zirconocene-ate Zwitterionic Complexes: Preparation and X-ray Structure

Zirconocen-Benzin-vermittelte intramolekulare Kupplung eines Bis(alkinyl)phosphans, ein Weg zu mono- und tricyclischen 1,2-Dihydrophospheten