6533b7d0fe1ef96bd125b7c3

RESEARCH PRODUCT

Visible-light photoelectrodegradation of diuron on WO3 nanostructures

B. Lucas-granadosJosé García-antónRita Sánchez-tovarM.j. Muñoz-porteroR.m. Fernández-domeneR. Ramírez-grau

subject

Environmental EngineeringMaterials scienceNanostructurechemistry.chemical_element02 engineering and technology010501 environmental sciencesManagement Monitoring Policy and LawTungsten01 natural sciencesINGENIERIA QUIMICAchemistry.chemical_compoundPesticidesHydrogen peroxideWaste Management and Disposal0105 earth and related environmental sciencesNanoestructuresAnodizingGeneral Medicine021001 nanoscience & nanotechnologyWO3 nanostructures AnodizationElectroquímicachemistryChemical engineeringDiuronKinetic coefficientDegradation (geology)Photoelectrocatalysis0210 nano-technologyFluorideVisible spectrum

description

[EN] The degradation of pesticide diuron has been explored by photoelectrocatalysis (PEC) under visible light illumination using two different WO3 nanostructures, obtained by anodization of tungsten. The highest degradation efficiency (73%) was obtained for WO3 nanosheets synthesized in the presence of small amounts of hydrogen peroxide (0.05 M). For that nanostructure, the kinetic coefficient for diuron degradation was 133% higher than that for the other nanostructure (anodized in the presence of fluoride anions). These results have been explained by taking into account the different architecture and dimensions of the two WO3 nanostructures under study.

10.1016/j.jenvman.2018.08.044https://hdl.handle.net/10550/76831