6533b7d1fe1ef96bd125c9c6

RESEARCH PRODUCT

Green conditions for the Suzuki reaction using microwave irradiation and a new HNT- supported ionic liquid-like phase (HNT-SILLP) catalyst

Marina MassaroSerena RielaGiuseppe LazzaraMichelangelo GruttadauriaStefana MiliotoRenato Noto

subject

microwaveSuzuki reactionHalloysite; Suzuki reaction; microwave; SILLP (supported ionic liquid-like phase)HalloysiteSILLP (supported ionic liquid-like phase)Settore CHIM/06 - Chimica OrganicaSettore CHIM/02 - Chimica Fisica

description

A new catalytic system based on modified halloysite nanotubes was employed in the Suzuki reaction under microwave irradi- ation. A set of solvents, times and bases was screened and the best experimental conditions were obtained when the reactions were carried out for 10 min in water–ethanol at 120 °C in presence of K2CO3 as base. Good recyclability was observed. The new catalytic system was employed using either 1 mol% or 0.1 mol%. The palladium catalyst displayed good activity, allowing the synthesis of several biphenyl compounds in high yield working with only 0.1 mol% palladium loading. The application of mi- crowave irradiation decreased the reaction time and also improved conversion with respect to traditional heating.

yearjournalcountryeditionlanguage
2014-02-10
10.1002/aoc.3114http://hdl.handle.net/10447/91363