6533b7d1fe1ef96bd125cb78

RESEARCH PRODUCT

Interfacial tension of demixed polymer solutions: augmentation by polymer additives

Bernhard A. WolfAnja Schneider

subject

chemistry.chemical_classificationTernary numeral systemMaterials sciencePolymers and PlasticsCyclohexanePolydimethylsiloxaneOrganic ChemistryPolymerSurface tensionchemistry.chemical_compoundchemistryChemical engineeringPhase (matter)Polymer chemistryMaterials ChemistryCopolymerPolystyrene

description

The interfacial tension between phase separated polymer solutions increases pronouncedly upon the addition of asmall amounts of incompatible polymers. This feature is demonstrated by means of measurements with solutions of polystyrene in cyclohexane and the folloowing additives: poly(styrene-block-dimethylsiloxane), polyisobutylene and polydimethylsiloxane. Theoretical considerations based on a correlation between the lenth of the tie lines and the corresponding interfacial tension corroborates this finding

https://doi.org/10.1002/marc.1997.030180705