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RESEARCH PRODUCT
Extended x-ray absorption fine structure spectroscopy and first-principles study of SnWO4
Janis TimoshenkoAndris AnspoksR. KalendarevAlexei KuzminAleksandr Kalinkosubject
Materials scienceExtended X-ray absorption fine structureAbsorption spectroscopyOctahedronDistortionTetrahedronSynchrotron radiationddc:530Atomic physicsCondensed Matter PhysicsSpectroscopyMathematical PhysicsAtomic and Molecular Physics and Opticsdescription
The local atomic structure in α- and β-SnWO 4 was studied bysynchrotron radiation W L 3 -edge X-ray absorption spectroscopy at 10 and 300 K.Strongly distorted WO 6 octahedra were found in α-SnWO 4 , whereas nearly regularWO 4 tetrahedra were observed in β-SnWO 4 , confirming previous results. Thestructural results obtained were supported by the first-principles calculations,suggesting that the second-order Jahn-Teller effect is responsible for octahedraldistortion.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-02-25 | Physica Scripta |