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6533b7d1fe1ef96bd125ce00

RESEARCH PRODUCT

Thermal Effects of Water Intrusion in Hydrophobic Nanoporous Materials.

Christian PaulinAnthony BallandrasJean-pierre BellatThomas KarbowiakGuy Weber

subject

NanostructureSurface PropertiesInorganic chemistry02 engineering and technologyCalorimetry010402 general chemistry01 natural sciencesBiochemistryEndothermic processCatalysisIsothermal process[PHYS.PHYS.PHYS-CHEM-PH] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Colloid and Surface ChemistryThermalPressureParticle SizeZeolitePorosityComputingMilieux_MISCELLANEOUSNanoporousChemistryTemperatureWaterGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesNanostructures[ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Chemical engineeringZeolitesParticle size[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]0210 nano-technologyHydrophobic and Hydrophilic InteractionsPorosity

description

Liquid water intrusion in hydrophobic nanoporous silicalite-1, a pure siliceous zeolite, in isothermal conditions under high pressure produces an endothermic effect. After intrusion, confined water in zeolite pores is in a different state from that of the liquid bulk water. Such forced intrusion also chemically modifies the material and tends to render it slightly more hydrophilic.

yearjournalcountryeditionlanguage
2009-01-01
https://hal.archives-ouvertes.fr/hal-00467831
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