Search results for "Nanoporous"
showing 10 items of 70 documents
Nanoporous characterization of modified humidity-sensitive MgO-Al 2 O 3 ceramics by positron annihilation lifetime spectroscopy method
2019
The work was supported by the Ukrainian Ministry of Education and Science. H. Klym thanks Prof. O. Shpotyuk for the fruitful discussion.
On the solution of a parabolic PDE involving a gas flow through a semi-infinite porous medium
2021
Abstract Taking as start point the parabolic partial differential equation with the respective initial and boundary conditions, the present research focuses onto the flow of a sample of waste-water derived from a standard/conventional dyeing process. In terms of a highly prioritized concern, meaning environment decontamination and protection, in order to remove the dyes from the waste waters, photocatalyses like ZnO or TiO2 nanoparticles were formulated, due to their high surface energy which makes them extremely reactive and attractive. According to the basics of ideal fluid, the key point is the gas flow through an ideal porous pipe consisting of nanoparticles bound one to each other, for…
Structure effects induced by high mechanical compaction of STAM-17-OEt MOF powders
2021
Financial support by PJ-RIC-FFABR_2017 and the EPSRC grant EPSRC industrial CASE award (grant EP/N50936X/1) are acknowledged. The research programme Nanoporous materials (P1-0021) financially supported by Slovenian Research Agency (ARRS) is acknowledged as well. Metal-organic frameworks (MOFs) are promising materials for many potential applications, spacing from gas storage to catalysis. However, the powder form of which they are generally made is not suitable, mainly because of the low packing density. Powder compaction is therefore necessary, but also challenging because of their typical mechanical fragility. Indeed, generally, they undergo irreversibly damages upon densification processe…
Study of Selective Adsorption of Gases by Calorimetry
2013
This chapter is devoted to the study of coadsorption of gases in nanoporous solids by using the differential calorimetry. In the first part, the thermodynamic principles of adsorption of gases are recalled. Some of them have already presented in chapter one. However a special attention has been paid here to the determination of the adsorption enthalpies and entropies and we focused on the selective adsorption of binary mixtures. Then the specific experimental technique based on the combination of differential calorimetry with manometry and gas phase chromatography or mass spectrometry is shown in details. In the last part, the thermodynamic concepts on coadsorption are illustrated with expe…
A new 8-oxo-7,8-2 ' deoxyguanosine nanoporous anodic alumina aptasensor for colorectal cancer diagnosis in blood and urine
2021
Many important human diseases, and especially cancer, have been related to the overproduction of 8-oxo-7,8-dihydro-2 '-deoxyguanosine (8-oxo-dG). This molecule is a product of oxidative stress processes over nucleophilic bases in DNA. In this work, an aptasensor for the rapid, selective and accurate detection of this oncomarker is presented. The aptasensor consists of a nanoporous anodic alumina material loaded with a dye and is functionalized with an aptamer-based "molecular gate". In the presence of target 8-oxo-dG, the capping aptamer displaces from the surface due to the high affinity of the analyte with the capping aptamer, thus inducing delivery of the preloaded fluorescent dye. In co…
Spectroelectrochemistry of cytochrome c and azurin immobilized in nanoporous antimony-doped tin oxide
2011
Stable immobilization of two redox proteins, cytochrome c and azurin, in a thin film of highly mesoporous antimony-doped tin oxide is demonstrated via UV-vis spectroscopic and electrochemical investigation.
Size-selective incorporation of DNA nanocages into nanoporous antimony-doped tin oxide materials.
2011
A conductive nanoporous antimony-doped tin oxide (ATO) powder has been prepared using the sol-gel method that contains three-dimensionally interconnected pores within the metal oxide and highly tunable pore sizes on the nanoscale. It is demonstrated that these porous materials possess the capability of hosting a tetrahedral-shaped DNA nanostructure of defined dimensions with high affinity. The tunability of pore size enables the porous substrate to selectively absorb the DNA nanostructures into the metal oxide cavities or exclude them from entering the surface layer. Both confocal fluorescence microscopy and solution FRET experiments revealed that the DNA nanostructures maintained their int…
Confident methods for the evaluation of the hydrogen content in nanoporous carbon microfibers
2012
Abstract Nanoporous carbon microfibers were grown by chemical vapor deposition in the vapor-liquid solid mode using different fluid hydrocarbons as precursors in different proportions. The as-grown samples were further treated in argon and hydrogen atmospheres at different pressure conditions and annealed at several temperatures in order to deduce the best conditions for the incorporation and re-incorporation of hydrogen into the microfibers through the nanopores. Since there are some discrepancies in the results on the hydrogen content obtained under vacuum conditions, in this work, we have measured the hydrogen content in the microfibers using several analytical methods in ambient conditi…
Pore Size Analysis of MCM-41 Type Adsorbents by Means of Nitrogen and Argon Adsorption
1998
Methods of nonlocal density functional theory (NLDFT), proposed recently for predictions of adsorption equilibrium and calculations of pore size distributions in micro- and mesoporous materials, were tested on reference MCM-41 materials. Five newly synthesized MCM-41 adsorbents with presumably uniform pore channels varying from 32 to 45 Å were characterized by X-ray diffraction (XRD), nitrogen adsorption at 77 K, and argon adsorption at 77 and 87 K. New sets of intermolecular interaction parameters of the NLDFT model for N2 and Ar adsorption on MCM-41 were determined. The parameters were specified to reproduce the bulk liquid-gas equilibrium densities and pressures, liquid-gas interfacial t…
Pt–CeO thin film catalysts for PEMFC
2015
Abstract Platinum is the mostly used element in catalysts for fuel cell technology, but its high price limits large-scale applications. Platinum doped cerium oxide represents an alternative solution due to very low loading, typically few micrograms per 1 cm2, at the proton exchange membrane fuel cell (PEMFC) anode. High efficiency is achieved by using magnetron sputtering deposition of cerium oxide and Pt of 30 nm thick nanoporous films on large surface carbon nanoparticle substrates. Thin film techniques permits to grow the catalyst film characterized by highly dispersed platinum, mostly in ionic Pt2+ state. Such dispersed Pt species show high activity and stability. These new materials ma…