6533b7d1fe1ef96bd125d944
RESEARCH PRODUCT
Crystal structure of the tetraaquabis(thiocyanato-kappa N)cobalt(II)-caffeine-water (1/2/4) co-crystal
Carine DuhayonCarine DuhayonM. El AmaneH. El Hamdanisubject
Hydrogen bondingSingle-crystal X-ray diffraction analysischemistry.chemical_elementThio-Crystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesResearch CommunicationsCrystallcsh:ChemistryCaffeineGeneral Materials Science[CHIM.COOR]Chemical Sciences/Coordination chemistrybiologyHydrogen bondCrystal structureGeneral ChemistryCondensed Matter Physicsbiology.organism_classification3. Good health0104 chemical sciencesCrystallographyOxygen atomchemistrylcsh:QD1-999TetraCobaltdescription
In the structure of the title compound, [Co(NCS)2(H2O)4]·2C8H10N4O2·4H2O, the cobalt metal lies on an inversion centre and is coordinated in a slightly distorted octahedral geometry. In the crystal, the complex molecules interact with the caffeine molecules through O—H⋯N, O—H⋯O, C–H⋯S hydrogen bonds and π–π interactions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-01-01 |