0000000000083330

AUTHOR

Carine Duhayon

0000-0001-7345-8782

showing 23 related works from this author

Inside Cover: Hydrogen-Bonded Open-Framework with Pyridyl-Decorated Channels: Straightforward Preparation and Insight into Its Affinity for Acidic Mo…

2017

International audience; A hydrogen-bonded open framework with pores decorated by pyridyl groups was constructed by off-charge-stoichiometry assembly of protonated tetrakis(4-pyridyloxymethyl)methane and [Al(oxalate)(3)](3-), which are the H-bond donor and acceptor of ionic H-bond interactions, respectively. This supramolecular porous architecture (SPA-2) has 1nm-large pores interconnected in 3D with large solvent-accessible void (53%). It demonstrated remarkable affinity for acidic organic molecules in solution, which was investigated by means of various carboxylic acids including larger drug molecules. Competing sorption between acetic acid and its halogenated homologues evidenced good sel…

porosityabsolute-structureHydrogenSupramolecular chemistrychemistry.chemical_element010402 general chemistry01 natural sciences[ CHIM ] Chemical SciencesCatalysissupramolecular chemistrycrystalhost-guest systemsPolymer chemistryMoleculesolid-state nmr[CHIM]Chemical Scienceshost frameworkssorption010405 organic chemistryHydrogen bondmicroporous materialsOrganic ChemistryarchitecturesSorptionGeneral Chemistrymetal-organic frameworkenantioselective separationOpen frameworkcations0104 chemical scienceschemistryadsorptionhydrogen bondsCover (algebra)
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Self-Assembly of Zr(C2O4)44– Metallotectons and Bisimidazolium Cations: Influence of the Dication on H-Bonded Framework Dimensionality and Material P…

2011

Assemblies involving [Zr(C2O4)4]4– metallotectons (C2O42– = oxalate) and linear, flexible, or V-shaped organic cations (H2-Lx)2+ derived from the 1,4-bisimidazol-1-ylbenzene molecule have been envisioned to elaborate porous frameworks based on ionic H-bonds. Five architectures of formula [{(H2-L1)2Zr(C2O4)4}·2H2O] (1), [{(H2-L2)2Zr(C2O4)4}·6H2O] (2), [{(H2-L3)2Zr(C2O4)4}·6H2O] (3), [{(H2-L4)2Zr(C2O4)4}·H2O] (4), and [{(H2-L5)2Zr(C2O4)4}·6H2O] (5) (with L1 = p-bis(imidazol-1-yl)benzene, L2 = p-bis(2-methylimidazol-1-yl)benzene, L3 = p-bis(imidazol-1-yl)-2,5-dimethylbenzene, L4 = p-bis(imidazol-1-ylmethyl)benzene, L5 = m-bis(imidazol-1-yl)benzene) have been obtained; 1–3, and 5 show an open-f…

StereochemistryIonic bondingGeneral ChemistryCondensed Matter PhysicsOxalateDicationchemistry.chemical_compoundCrystallographychemistryMoleculeGeneral Materials ScienceSelf-assemblyBenzenePorosityCurse of dimensionalityCrystal Growth & Design
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Crystal structure of the tetraaquabis(thiocyanato-kappa N)cobalt(II)-caffeine-water (1/2/4) co-crystal

2017

In the structure of the title compound, [Co(NCS)2(H2O)4]·2C8H10N4O2·4H2O, the cobalt metal lies on an inversion centre and is coordinated in a slightly distorted octa­hedral geometry. In the crystal, the complex mol­ecules inter­act with the caffeine mol­ecules through O—H⋯N, O—H⋯O, C–H⋯S hydrogen bonds and π–π inter­actions.

Hydrogen bondingSingle-crystal X-ray diffraction analysischemistry.chemical_elementThio-Crystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesResearch CommunicationsCrystallcsh:ChemistryCaffeineGeneral Materials Science[CHIM.COOR]Chemical Sciences/Coordination chemistrybiologyHydrogen bondCrystal structureGeneral ChemistryCondensed Matter Physicsbiology.organism_classification3. Good health0104 chemical sciencesCrystallographyOxygen atomchemistrylcsh:QD1-999TetraCobalt
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Tris(1,10-phenanthroline-κ2N,N′)nickel(II) bis(hexafluoridophosphate)

2018

The asymmetric unit of the title compound, [Ni(C36H24N6)3](PF6)2, contains one and a half nickel(II) complex dications and three hexafluoridophosphate anions, one of the dications having crystallographic twofold rotational symmetry. Each NiIIatom displays a distorted octahedral coordination geometry provided by the six N atoms of three bidentate 1,10-phenanthroline ligands with bite angles of 79.68 (11)–80.76 (12)°. In the crystal, C—H...F hydrogen bonds link the anions and dications into a three-dimensional supramolecular framework. Within the framework complex dications with twofold rotational symmetry are linked by weak π–π stacking interactions [centroid-to-centroid distances = 3.712 (2…

crystal structurehexafluoridophosphateDenticity110-phenanthrolineChemistryHydrogen bondPhenanthrolineStackingchemistry.chemical_elementGeneral MedicineCrystal structure010402 general chemistry010403 inorganic & nuclear chemistryHEXAhydrogen bonding01 natural sciences0104 chemical scienceschemistry.chemical_compoundNickelCrystallographylcsh:QD901-999lcsh:Crystallographynickel(II)Coordination geometryIUCrData
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Hydrogen-Bonded Open-Framework with Pyridyl-Decorated Channels: Straightforward Preparation and Insight into Its Affinity for Acidic Molecules in Sol…

2017

International audience; An hydrogen-bonded open framework with pores decorated by pyridyl groups has been constructed following an off-charge-stoichiometry assemblage of protonated tetrakis(4-pyridyl-oxymethyl)methane and [Al(oxalate)3]3-, respectively the H-bond donor and acceptor of the ionic H-bond interactions. This supramolecular porous architecture (SPA-2) possesses 1 nm-large pores interconnected in 3D with high solvent accessible void (53%). It demonstrated remarkable affinity for acidic organic molecules in solution, which was investigated by the means of various carboxylic acids including larger drug molecules. Noteworthy, competing sorption between acetic acid and its halogenated…

010405 organic chemistryHydrogen bondChemistryOrganic ChemistrySupramolecular chemistryIonic bondingProtonationSorptionGeneral ChemistryHydrogen-Bonding010402 general chemistry[ CHIM ] Chemical Sciences01 natural sciencessupramolecular chemistryCatalysis0104 chemical sciencesSolventPolymer chemistryhost-guest chemistry[CHIM]Chemical SciencesMoleculeOrganic chemistryoxalate complexporous materialHost–guest chemistryChemistry (Weinheim an der Bergstrasse, Germany)
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A robust nanoporous supramolecular metal–organic framework based on ionic hydrogen bonds

2014

International audience; Hydrogen-bond assembly of tripod-like organic cations [H3-MeTrip]3+ (1,2,3-tri(4′-pyridinium-oxyl)-2-methylpropane) and the hexa-anionic complex [Zr2(oxalate)7]6− leads to a structurally, thermally, and chemically robust porous 3D supramolecular framework showing channels of 1 nm in width. Permanent porosity has been ascertained by analyzing the material at the single-crystal level during a sorption cycle. The framework crystal structure was found to remain the same for the native compound, its activated phase, and after guest resorption. The channels exhibit affinities for polar organic molecules ranging from simple alcohols to aniline. Halogenated molecules and I2 …

chemistry.chemical_classification010405 organic chemistryChemistryNanoporousOrganic ChemistryInorganic chemistrySupramolecular chemistryIonic bondingGeneral Chemistry010402 general chemistryCrystal engineering01 natural sciencesCatalysis0104 chemical sciencesSupramolecular assemblySupramolecular polymersChemical engineeringMoleculeMetal-organic framework[CHIM.COOR]Chemical Sciences/Coordination chemistry
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Supramolecular open-framework architectures based on dicarboxylate H-bond acceptors and polytopic cations with three/four N–H+donor units

2015

International audience; Supramolecular assemblages based on anionic H-acceptors and cationic H-donors have been envisioned to elaborate open frameworks maintained by ionic H-bonds. Combinations of di-anionic chloranilate (CA2-), oxalate (Ox2-), or terephthalate (BDC2-) and trisimidazolium or tetrapyridinium derivatives (three and four N-H+ donors, respectively) yielded five architectures of formulae [(H3TrIB)(CA)1.5[middle dot]2DMF[middle dot]2.5H2O] (1), [(H4Tetrapy)(CA)2[middle dot]3DMF] (2), [(H3TrIB)(HOx)(Ox)[middle dot]5H2O] (3), [(H4Tetrapy)(Ox)2[middle dot]5H2O] (4), and [(H4Tetrapy)(BDC)2(H2O)[middle dot]1DMF[middle dot]3H2O] (5) (with TrIB = 1,3,5-trisimidazolylbenzene and Tetrapy …

010405 organic chemistryChemistryStereochemistryHydrogen bondSupramolecular chemistryCationic polymerizationIonic bondingSorptionGeneral ChemistryCrystal structure010402 general chemistryCondensed Matter Physics01 natural sciencesOxalate0104 chemical sciencesSolventchemistry.chemical_compoundCrystallography[CHIM.COOR]Chemical Sciences/Coordination chemistryGeneral Materials ScienceCrystEngComm
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CCDC 1402188: Experimental Crystal Structure Determination

2015

Related Article: Georges Mouchaham, Marion Gualino, Nans Roques, Carine Duhayon, Stéphane Brandès, Jean-Pascal Sutter|2015|CrystEngComm|17|8906|doi:10.1039/C5CE01070E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-((22-bis(((pyridin-1-ium-4-yl)oxy)methyl)propane-13-diyl)bis(oxy))di(pyridin-1-ium) bis(terephthalate) NN-dimethylformamide solvate tetrahydrateExperimental 3D Coordinates
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CCDC 1537659: Experimental Crystal Structure Determination

2017

Related Article: Georges Mouchaham, Nans Roques, Walid Khodja, Carine Duhayon, Yannick Coppel, Stéphane Brandès, Tamás Fodor, Michel Meyer and Jean-Pascal Sutter|2017|Chem.-Eur.J.|23|11818|doi:10.1002/chem.201701732

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-((2-(((pyridin-1-ium-4-yl)oxy)methyl)-2-(((pyridin-4-yl)oxy)methyl)propane-13-diyl)bis(oxy))di(pyridin-1-ium) tris(oxalato)-aluminium trichloroacetic acid hydrateExperimental 3D Coordinates
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CCDC 993985: Experimental Crystal Structure Determination

2014

Related Article: Nans Roques, Georges Mouchaham, Carine Duhayon, Stéphane Brandès, Aurélie Tachon, Guy Weber, Jean Pierre Bellat, Jean-Pascal Sutter|2014|Chem.-Eur.J.|20|11690|doi:10.1002/chem.201403638

Space GroupCrystallographybis(123-tris((Pyridinium-4-yl)oxy)-2-methylpropane) (mu~2~-oxalato)-hexakis(oxalato)-di-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 993988: Experimental Crystal Structure Determination

2014

Related Article: Nans Roques, Georges Mouchaham, Carine Duhayon, Stéphane Brandès, Aurélie Tachon, Guy Weber, Jean Pierre Bellat, Jean-Pascal Sutter|2014|Chem.-Eur.J.|20|11690|doi:10.1002/chem.201403638

Space GroupCrystallographyCrystal SystemCrystal Structurebis(123-tris((Pyridinium-4-yl)oxy)-2-methylpropane) (mu~2~-oxalato)-hexakis(oxalato)-di-zirconium di-iodine clathrateCell ParametersExperimental 3D Coordinates
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CCDC 993987: Experimental Crystal Structure Determination

2014

Related Article: Nans Roques, Georges Mouchaham, Carine Duhayon, Stéphane Brandès, Aurélie Tachon, Guy Weber, Jean Pierre Bellat, Jean-Pascal Sutter|2014|Chem.-Eur.J.|20|11690|doi:10.1002/chem.201403638

Space GroupCrystallographyCrystal SystemCrystal Structurebis(123-tris((Pyridinium-4-yl)oxy)-2-methylpropane) (mu~2~-oxalato)-hexakis(oxalato)-di-zirconium hydrateCell ParametersExperimental 3D Coordinates
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CCDC 1402184: Experimental Crystal Structure Determination

2015

Related Article: Georges Mouchaham, Marion Gualino, Nans Roques, Carine Duhayon, Stéphane Brandès, Jean-Pascal Sutter|2015|CrystEngComm|17|8906|doi:10.1039/C5CE01070E

Space GroupCrystallography11'1''-benzene-135-triyltris(1H-imidazol-3-ium) sesquikis(25-dichloro-36-dioxocyclohexa-14-diene-14-diolate) NN-dimethylformamide solvate hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 993983: Experimental Crystal Structure Determination

2014

Related Article: Nans Roques, Georges Mouchaham, Carine Duhayon, Stéphane Brandès, Aurélie Tachon, Guy Weber, Jean Pierre Bellat, Jean-Pascal Sutter|2014|Chem.-Eur.J.|20|11690|doi:10.1002/chem.201403638

Space GroupCrystallographyCrystal SystemCrystal Structurebis(123-tris((Pyridinium-4-yl)oxy)-2-methylpropane) (mu~2~-oxalato)-hexakis(oxalato)-di-zirconium hydrateCell ParametersExperimental 3D Coordinates
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CCDC 993984: Experimental Crystal Structure Determination

2014

Related Article: Nans Roques, Georges Mouchaham, Carine Duhayon, Stéphane Brandès, Aurélie Tachon, Guy Weber, Jean Pierre Bellat, Jean-Pascal Sutter|2014|Chem.-Eur.J.|20|11690|doi:10.1002/chem.201403638

Space GroupCrystallographyCrystal SystemCrystal Structurebis(123-tris((Pyridinium-4-yl)oxy)-2-methylpropane) (mu~2~-oxalato)-hexakis(oxalato)-di-zirconium hydrateCell ParametersExperimental 3D Coordinates
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CCDC 1537661: Experimental Crystal Structure Determination

2017

Related Article: Georges Mouchaham, Nans Roques, Walid Khodja, Carine Duhayon, Yannick Coppel, Stéphane Brandès, Tamás Fodor, Michel Meyer and Jean-Pascal Sutter|2017|Chem.-Eur.J.|23|11818|doi:10.1002/chem.201701732

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-((2-(((pyridin-1-ium-4-yl)oxy)methyl)-2-(((pyridin-4-yl)oxy)methyl)propane-13-diyl)bis(oxy))di(pyridin-1-ium) tris(oxalato)-aluminium acetic acid hydrateExperimental 3D Coordinates
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CCDC 1537660: Experimental Crystal Structure Determination

2017

Related Article: Georges Mouchaham, Nans Roques, Walid Khodja, Carine Duhayon, Yannick Coppel, Stéphane Brandès, Tamás Fodor, Michel Meyer and Jean-Pascal Sutter|2017|Chem.-Eur.J.|23|11818|doi:10.1002/chem.201701732

Space GroupCrystallographyCrystal SystemCrystal Structure44'-((2-(((pyridin-1-ium-4-yl)oxy)methyl)-2-(((pyridin-4-yl)oxy)methyl)propane-13-diyl)bis(oxy))di(pyridin-1-ium) tris(oxalato)-aluminium trifluoroacetic acid hydrateCell ParametersExperimental 3D Coordinates
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CCDC 1537663: Experimental Crystal Structure Determination

2017

Related Article: Georges Mouchaham, Nans Roques, Walid Khodja, Carine Duhayon, Yannick Coppel, Stéphane Brandès, Tamás Fodor, Michel Meyer and Jean-Pascal Sutter|2017|Chem.-Eur.J.|23|11818|doi:10.1002/chem.201701732

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-((2-(((pyridin-1-ium-4-yl)oxy)methyl)-2-(((pyridin-4-yl)oxy)methyl)propane-13-diyl)bis(oxy))di(pyridin-1-ium) tris(oxalato)-aluminium hydrateExperimental 3D Coordinates
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CCDC 1402187: Experimental Crystal Structure Determination

2015

Related Article: Georges Mouchaham, Marion Gualino, Nans Roques, Carine Duhayon, Stéphane Brandès, Jean-Pascal Sutter|2015|CrystEngComm|17|8906|doi:10.1039/C5CE01070E

Space GroupCrystallography4-{3-(pyridinium-4-yloxy)-22-bis[(pyridinium-4-yloxy)methyl]propoxy}pyridinium bis(oxalate) pentahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 993986: Experimental Crystal Structure Determination

2014

Related Article: Nans Roques, Georges Mouchaham, Carine Duhayon, Stéphane Brandès, Aurélie Tachon, Guy Weber, Jean Pierre Bellat, Jean-Pascal Sutter|2014|Chem.-Eur.J.|20|11690|doi:10.1002/chem.201403638

Space GroupCrystallographyCrystal SystemCrystal Structurebis(123-tris((Pyridinium-4-yl)oxy)-2-methylpropane) (mu~2~-oxalato)-hexakis(oxalato)-di-zirconium hydrateCell ParametersExperimental 3D Coordinates
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CCDC 1537662: Experimental Crystal Structure Determination

2017

Related Article: Georges Mouchaham, Nans Roques, Walid Khodja, Carine Duhayon, Yannick Coppel, Stéphane Brandès, Tamás Fodor, Michel Meyer and Jean-Pascal Sutter|2017|Chem.-Eur.J.|23|11818|doi:10.1002/chem.201701732

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-((22-bis(((pyridin-1-ium-4-yl)oxy)methyl)propane-13-diyl)bis(oxy))di(pyridin-1-ium) tris(oxalato)-aluminium nitrate hydrateExperimental 3D Coordinates
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CCDC 1402186: Experimental Crystal Structure Determination

2015

Related Article: Georges Mouchaham, Marion Gualino, Nans Roques, Carine Duhayon, Stéphane Brandès, Jean-Pascal Sutter|2015|CrystEngComm|17|8906|doi:10.1039/C5CE01070E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11'1''-benzene-135-triyltris-1H-imidazol-3-ium hydrogen ethanedioate ethanedioate pentahydrateExperimental 3D Coordinates
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CCDC 1402185: Experimental Crystal Structure Determination

2015

Related Article: Georges Mouchaham, Marion Gualino, Nans Roques, Carine Duhayon, Stéphane Brandès, Jean-Pascal Sutter|2015|CrystEngComm|17|8906|doi:10.1039/C5CE01070E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters44'-((22-bis(((pyridin-1-ium-4-yl)oxy)methyl)propane-13-diyl)bis(oxy))di(pyridin-1-ium) bis(25-dichloro-36-dioxocyclohexa-14-diene-14-diolate) NN-dimethylformamide solvateExperimental 3D Coordinates
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