6533b821fe1ef96bd127af98
RESEARCH PRODUCT
Tris(1,10-phenanthroline-κ2N,N′)nickel(II) bis(hexafluoridophosphate)
H. El HamdaniCarine DuhayonCarine DuhayonM. El Amanesubject
crystal structurehexafluoridophosphateDenticity110-phenanthrolineChemistryHydrogen bondPhenanthrolineStackingchemistry.chemical_elementGeneral MedicineCrystal structure010402 general chemistry010403 inorganic & nuclear chemistryHEXAhydrogen bonding01 natural sciences0104 chemical scienceschemistry.chemical_compoundNickelCrystallographylcsh:QD901-999lcsh:Crystallographynickel(II)Coordination geometrydescription
The asymmetric unit of the title compound, [Ni(C36H24N6)3](PF6)2, contains one and a half nickel(II) complex dications and three hexafluoridophosphate anions, one of the dications having crystallographic twofold rotational symmetry. Each NiIIatom displays a distorted octahedral coordination geometry provided by the six N atoms of three bidentate 1,10-phenanthroline ligands with bite angles of 79.68 (11)–80.76 (12)°. In the crystal, C—H...F hydrogen bonds link the anions and dications into a three-dimensional supramolecular framework. Within the framework complex dications with twofold rotational symmetry are linked by weak π–π stacking interactions [centroid-to-centroid distances = 3.712 (2) Å].
year | journal | country | edition | language |
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2018-05-01 | IUCrData |