6533b86dfe1ef96bd12c978a
RESEARCH PRODUCT
A robust nanoporous supramolecular metal–organic framework based on ionic hydrogen bonds
J. P. BellatAurélie TachonCarine DuhayonCarine DuhayonGuy WeberStéphane BrandèsNans RoquesNans RoquesJean-pascal SutterJean-pascal SutterGeorges MouchahamGeorges Mouchahamsubject
chemistry.chemical_classification010405 organic chemistryChemistryNanoporousOrganic ChemistryInorganic chemistrySupramolecular chemistryIonic bondingGeneral Chemistry010402 general chemistryCrystal engineering01 natural sciencesCatalysis0104 chemical sciencesSupramolecular assemblySupramolecular polymersChemical engineeringMoleculeMetal-organic framework[CHIM.COOR]Chemical Sciences/Coordination chemistrydescription
International audience; Hydrogen-bond assembly of tripod-like organic cations [H3-MeTrip]3+ (1,2,3-tri(4′-pyridinium-oxyl)-2-methylpropane) and the hexa-anionic complex [Zr2(oxalate)7]6− leads to a structurally, thermally, and chemically robust porous 3D supramolecular framework showing channels of 1 nm in width. Permanent porosity has been ascertained by analyzing the material at the single-crystal level during a sorption cycle. The framework crystal structure was found to remain the same for the native compound, its activated phase, and after guest resorption. The channels exhibit affinities for polar organic molecules ranging from simple alcohols to aniline. Halogenated molecules and I2 are also taken up from hexane solutions by this unique supramolecular framework.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-01-01 |