6533b7d2fe1ef96bd125dedd

RESEARCH PRODUCT

A New Rhodium(III) Complex with a Tripodal Bis(imidazolylidene) Ligand. Synthesis and Catalytic Properties

Mercedes SanaúEduardo PerisElena Mas-marzáMacarena Poyatos

subject

ChemistryStereochemistryLigandOrganic ChemistryHydrogen transferchemistry.chemical_elementRhodiumCatalysisInorganic Chemistrychemistry.chemical_compoundTripodal ligandPolymer chemistryPhysical and Theoretical ChemistryCarbene

description

A new bis(imidazolylidene) tripodal ligand has been obtained by a simple method. The coordination of this ligand to Rh provides the first Rh(III) complex with a bis(carbene) ligand in a tripodal coordination, and its catalytic properties toward hydrogen transfer have been examined.

https://doi.org/10.1021/om0341552