6533b7d2fe1ef96bd125df9c

RESEARCH PRODUCT

Aryl radicals by copper(II) oxidation of hydrazines: A new method for the oxidative and reductive arylation of alkenes

Javier Rodrigo-chinerMaría Elena González-núñezGregorio AsensioTeresa Varea

subject

chemistry.chemical_compoundchemistryRadicalArylOrganic ChemistryDrug Discoverychemistry.chemical_elementOrganic chemistryOxidative phosphorylationSulfateBiochemistryMedicinal chemistryCopper

description

Abstract A new source of aryl radicals interesting from the preparative point of view has been found in the reaction of arylhydrazines and copper(II) sulfate. The process allows selectively both the reductive and oxidative arylation of alkenes.

https://doi.org/10.1016/s0040-4039(01)80781-4