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RESEARCH PRODUCT
Syntheses, Structures and Reactivity of New Intramolecularly Coordinated Tin Alkoxides Based on an Enantiopure Ephedrine Derivative
Klaus JurkschatDieter SchollmeyerChristina DietzLjuba Iovkova-berendsGerrit BradtmöllerThorsten Berendssubject
ChemistryStereochemistryElectrospray ionizationchemistry.chemical_elementNuclear magnetic resonance spectroscopyMedicinal chemistryInorganic Chemistrychemistry.chemical_compoundEnantiopure drugElemental analysisReactivity (chemistry)TinSingle crystalDerivative (chemistry)description
The syntheses of the tin compounds [LSn]2 (2), spiro-L2Sn (3), [LSnW(CO)5]2 (4), [LSnBr2]2 (5), spiro-L2Sn·SnBr4 (6) and LSn[OC(O)Ph]2 (8), where L = MeN(CH2CMe2O)[(S)-CH(Me)-(R)-CH(Ph)O], and (Ph4P)2SnBr6 (7) are reported. The compounds were characterized by elemental analysis, multinuclear NMR spectroscopy including 119Sn cross polarisation–magic angle spinning NMR (CP–MAS) (2, 3–6), electrospray ionization mass spectrometry (2–4) and single crystal X-ray diffraction analysis (2, 2·C7H8, 3a, 3b, 4·C7H8, 5, 6·C7H8, 7).
year | journal | country | edition | language |
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2011-07-21 | European Journal of Inorganic Chemistry |