6533b7d2fe1ef96bd125f66e
RESEARCH PRODUCT
Colloidal stability of nanoparticles derived from simulated cloud-processed mineral dusts
Andrew FisherSergio CalabreseZongbo ShiJamie R. LeadJamie R. LeadEugenia Valsami-jonesEniko KadarBjörn Stolpesubject
Environmental EngineeringGoethiteChemistryNanoparticleAtmospheric depositionPollutionNanomaterialsFerrihydriteColloidNanoparticleAtmospheric deposition Ferrihydrite Nanoparticle Dissolutionvisual_artEnvironmental chemistryvisual_art.visual_art_mediumFerrihydriteEnvironmental ChemistryParticleWaste Management and DisposalDissolutionDissolutionVolcanic ashdescription
AbstractLaboratory simulation of cloud processing of three model dust types with distinct Fe-content (Moroccan dust, Libyan dust and Etna ash) and reference goethite and ferrihydrite were conducted in order to gain a better understanding of natural nanomaterial inputs and their environmental fate and bioavailability. The resulting nanoparticles (NPs) were characterised for Fe dissolution kinetics, aggregation/size distribution, micromorphology and colloidal stability of particle suspensions using a multi-method approach. We demonstrated that the: (i) acid-leachable Fe concentration was highest in volcanic ash (1mMg−1 dust) and was followed by Libyan and Moroccan dust with an order of magnitude lower levels; (ii) acid leached Fe concentration in theLibyan dust). The common occurrence of Fe-rich “natural nanoparticles” in atmospheric dust derived materials may indicate their more ubiquitous presence in the marine environment than previously thought.
year | journal | country | edition | language |
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2013-07-16 | Science of The Total Environment |