6533b7d2fe1ef96bd125f72c

RESEARCH PRODUCT

Magnetoresistance studies of the ferromagnetic molecular metal (BEDT-TTF)3[MnCr(C2O4)3] under pressure

A.-k. KleheEugenio CoronadoJohn SingletonJosé Ramón Galán-mascarósCarlos J. Gómez-garcíaV.n. LauhkinJ. A. SymingtonPaul GoddardCarlos Giménez-saizJ. Aghassi

subject

MagnetoresistanceCondensed matter physicsChemistryMagnetismMechanical EngineeringHydrostatic pressureMetals and AlloysConductivityCondensed Matter PhysicsThermal conductionShubnikov–de Haas effectElectronic Optical and Magnetic MaterialsMagnetic fieldFerromagnetismMechanics of MaterialsMaterials Chemistry

description

(BEDT-TTF)3[MnCr(C2O4)3] is the first ferromagnetic molecular metal, in which organic layers of BEDT-TTF alternate with infinite layers of the bimetallic oxalate complex [MnCr(C2O4)3]-. While the bimetallic layer undergoes a magnetic phase transition into a canted ferromagnetic state at 5.5 K, the metallic character of the conductivity is not affected by the magnetic transition [Nature 408 (2000) 447]. We performed magnetoresistance measurements (B≤17 T) at low temperatures (T≥900 mK) and under hydrostatic pressures of up to 2.0 GPa. Oscillations in the magnetoresistance develop under pressure that can be interpreted as Shubnikov-de Haas oscillations, if an internal magnetic field is taken into account. These measurements can thus be interpreted as a measure of the internal magnetic field in the conduction layer caused by the adjacent magnetic oxalate layers. © 2002 Elsevier Science B.V. All rights reserved.

https://doi.org/10.1016/s0379-6779(02)00342-9