6533b7d3fe1ef96bd125fece

RESEARCH PRODUCT

Host–guest blue light-emitting electrochemical cells

Henk J. BolinkMohammad Khaja NazeeruddinAntonio PertegásEnrique OrtíNail M. ShavaleevDaniel Tordera

subject

Organic electronicsMaterials scienceCarbazoleInorganic chemistryIonic bondingGeneral ChemistryElectroluminescenceElectrochemical cellchemistry.chemical_compoundchemistryHexafluorophosphateMaterials ChemistryCommon emitterBlue light

description

Carbazole, a commonly used hole-transporter for organic electronics, has been modified with an imidazolium cation and a hexafluorophosphate counter-anion to give an ionic hole-transporter. It has been applied as one of the hosts in a host–guest blue light-emitting electrochemical cell (LEC) with the neutral blue emitter FIrPic. We have obtained efficient and bright blue LECs with an electroluminescence maximum at 474 nm and efficacy of 5 cd A−1 at a luminance of 420 cd m−2, thereby demonstrating the potential of the ionic organic charge-transporters and of the host–guest architecture for LECs.

https://doi.org/10.1039/c3tc31983k