6533b7d3fe1ef96bd1260a9f

RESEARCH PRODUCT

Field-induced slow magnetic relaxation and magnetocaloric effects in an oxalato-bridged gadolinium(iii)-based 2D MOF

José Martínez-lilloIsabel CastroMarta Orts-arroyoRenato RabeloRafael Ruiz-garcíaJúlia MayansJoan CanoNicolás MolinerAinoa Carrasco-berlangaMiguel JulveFrancesc LloretGiovanni De Munno

subject

Inorganic ChemistryMaterials scienceCondensed matter physicschemistryField (physics)Feature (computer vision)GadoliniumMagnetic refrigerationchemistry.chemical_elementMagnetic relaxation

description

The coexistence of field-induced slow magnetic relaxation and moderately large magnetocaloric efficiency in the supra-Kelvin temperature region occurs in the 2D compound [GdIII2(ox)3(H2O)6]n·4nH2O (1), a feature that can be exploited in the proof-of-concept design of a new class of slow-relaxing magnetic materials for cryogenic magnetic refrigeration.

https://doi.org/10.1039/d1dt00462j