6533b7d3fe1ef96bd1261310
RESEARCH PRODUCT
Thiophen—Mangantricarbonyl-Komplexe
Hellmut Singersubject
Inorganic ChemistryNMR spectra databasechemistry.chemical_compoundChemistryOrganic ChemistryMaterials ChemistryCationic polymerizationThiopheneOrganic chemistryEtherPhysical and Theoretical ChemistryBiochemistryMedicinal chemistrydescription
Abstract Cationic thiophenemanganese tricabonyl complexes of the formula [C 4 (CH 3 ) x H 4- x S Mn(CO) 3 ] + have been prepared with 2-methyl-, 3-methyl-, 2,5-dimethyl-, 2,3,5-trimethyl-, tetramethylthiophene, and with thiophene by the reaction of Mn(CO) 5 Cl+AlCl 3 or AlBr 3 with the thiophenes in petrol ether, at 100–110°. The complexions give yellow solutions which are fairly stable. Their IR and some NMR spectra are given and discussed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1967-07-01 | Journal of Organometallic Chemistry |