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RESEARCH PRODUCT
More electron rich than cyclopentadienyl: 1,2-diaza-3,5-diborolyl as a ligand in ferrocene and ruthenocene analogs
Heikki M. TuononenHanh V. LyMasood ParvezJani O. MoilanenRoland Roeslersubject
LigandMetal ions in aqueous solutionMetals and Alloyschemistry.chemical_elementGeneral ChemistryElectronPhotochemistryElectrochemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsRutheniumchemistry.chemical_compoundCyclopentadienyl complexFerrocenechemistryPolymer chemistryMaterials ChemistryCeramics and CompositesRuthenoceneta116description
Ruthenium and iron sandwich complexes incorporating cyclopentadienyl analogs with CB(2)N(2)(-) skeletons were characterized. Electrochemical measurements supported by computational studies revealed that in combination with larger metal ions such as Ru the CB(2)N(2)(-) ligand can be more electron-rich than its organic counterpart.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-06-28 | Chemical Communications |