6533b7d4fe1ef96bd1263136
RESEARCH PRODUCT
Molecular hybrids formed by oxalate bridged dinuclear anions and organometallic cations
J. Sala PalaCarlos J. Gómez-garcíaF. BérézovskyEugenio CoronadoJosé Ramón Galán-mascarósSmail Trikisubject
Magnetic measurementsStereochemistryChemistryMechanical EngineeringMetals and AlloysInfrared spectroscopychemistry.chemical_elementCrystal structureCondensed Matter PhysicsMagnetic susceptibilityOxalateElectronic Optical and Magnetic MaterialsCrystallographyChromiumchemistry.chemical_compoundMechanics of MaterialsMaterials ChemistryMoleculedescription
Abstract The syntheses, magnetic properties and infrared spectra of a new series of molecular hybrids formed by association of two magnetic sublattices: (i) oxalate bridged dinuclear anions [V 2 O 2 (ox)(NCS) 6 ] 4− and [M′M′'(ox)(NCS) 8 ] 4 ( M′= Fe III , Cr III ; M′' - Fe III , Cr III ; ox 2 = C 2 O 4 2 and (ii) decamethylferrocenium organometallic cation are presented. The crystal structure of [Fe(Cp * ) 2 ][(C 2 H 5 ) 4 N] 2 [V 2 O 2 (ox)(NCS) 6 ] is also discussed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-06-01 | Synthetic Metals |