6533b7d4fe1ef96bd126354c

RESEARCH PRODUCT

Interactions between 2-Aminobenzothiazole and Natural Organic Matter as Evidenced by CPMAS Nitrogen-15 NMR Spectroscopy

E. G. WitteHerbert PhilippPellegrino ConteH. LewandowskiAnne E. Berns

subject

chemistry.chemical_classificationHydrogen bondSettore AGR/13 - Chimica AgrariaHASoil Science2-aminobenzothiazolenuclear magnetic resonance.Nuclear magnetic resonance spectroscopyCPMAShumic acidCarbon-13 NMRABTNMRchemistry.chemical_compoundchemistryCovalent bondMagic angle spinningOrganic chemistryOrganic mattercross-polarization magic angle spinningHPLChigh-performance liquid chromatographyThiazoleSpectroscopy

description

Cross-polarization magic angle spinning (CPMAS) 15N nuclear magnetic resonance (NMR) spectroscopy was used to study the interactions between 2-aminobenzothiazole (ABT) and natural organic matter in the presence of the natural enzyme laccase and synthetic air. Through the use of synthesized model compounds, we were able to confirm previous findings by CPMAS 13C NMR spectroscopy that showed the formation of covalent amide bonds. We also provide evidence of the presence of two additional H bonds between ABT and the natural organic matter. Both H bonds involved the amino and thiazole groups of ABT.

yearjournalcountryeditionlanguage
2009-08-01
10.2136/vzj2008.0026http://hdl.handle.net/10447/39002