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RESEARCH PRODUCT
Controlled Synthesis of Reactive Polymeric Architectures Using 5-Norbornene-2-carboxylic Acid Pentafluorophenyl Ester
Nicolas VogelPatrick Theatosubject
chemistry.chemical_classificationMaterials scienceCondensation polymerPolymers and PlasticsCarboxylic acidOrganic ChemistryPolymerCondensed Matter PhysicsMetathesischemistry.chemical_compoundMonomerchemistryPolymerizationPolymer chemistryMaterials ChemistryLiving polymerizationOrganic chemistryNorbornenedescription
Exo-5-norbornene-2-carboxylic acid pentafluorophenyl ester was synthesized from 5-norbornene-2-carboxylic acid and polymerized by ring-opening metathesis polymerization. The obtained polymers were soluble polymeric active esters that could be used for the preparation of multifunctional polymers. The molecular weight of the polymers was controlled by variation of the monomer to initiator ratio. The precursor polymers reacted quantitatively with primary and secondary amines. Time resolved FT-IR studies at different temperatures of the polymer analogous reactions were performed and rate constants were determined.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-04-01 | Macromolecular Symposia |