6533b7d5fe1ef96bd12645e1

RESEARCH PRODUCT

Clathration effects on the interpenetration in the 2D (4,4) coordination polymer {[Fe(4,4 ′ -bipy)(dca) 2 ] · bt}

José Antonio RealAna B. GasparMuñoz Mc

subject

Inorganic Chemistrychemistry.chemical_classificationchemistry.chemical_compoundCrystallographychemistryCoordination polymerSelf assemblingMaterials ChemistryPolymerCrystal structurePhysical and Theoretical ChemistryDicyanamide

description

Abstract A novel 2D polymer, {[Fe(4,4′-bipy)(dca)2] · bt}, (dca=dicyanamide, 4,4′-bipy=4,4′-bipyridine and bt=2,2′-bithiazoline) has been synthesized and characterized by X-ray crystallography. The structure reveals the formation of 2D (4,4) networks and intercalated bt uncoordinated ligands.

https://doi.org/10.1016/j.inoche.2004.05.005