6533b7d5fe1ef96bd12646b0

RESEARCH PRODUCT

Self-organized nanostructures of poly(4-vinylpyridine), polyaniline and polyamides due to metal complexation

Janne RuokolainenMika TorkkeliGerrit Ten BrinkeSami ValkamaJuha HartikainenKari RissanenRitva SerimaaOlli Ikkala

subject

chemistry.chemical_classificationConductive polymerCOORDINATIONMaterials sciencePolymers and PlasticsHydrogen bondOrganic Chemistrychemistry.chemical_elementZincPolymerConjugated systemCondensed Matter PhysicsMetalchemistry.chemical_compoundchemistrySUPRAMOLECULAR POLYMERIC MATERIALSSYSTEMSvisual_artPolyanilinePolymer chemistryPolyamideComputingMethodologies_DOCUMENTANDTEXTPROCESSINGMaterials Chemistryvisual_art.visual_art_mediumGeneralLiterature_REFERENCE(e.g.dictionariesencyclopediasglossaries)

description

Comb-shaped supramolecules are constructed using flexible polymers and semi-rigid conjugated undoped or doped conjugated polymers upon complexing Zinc dodecyl benzene sulphonate, Zn(DBS) 2 . Self-organized nanostructures are formed in the bulk due to competing attractive interactions (coordination or water mediated hydrogen bonding) and repulsive polar/nonpolar interactions, showing characteristic long periods of ca. 30 A.

10.1002/1521-3900(200208)186:1<87::aid-masy87>3.0.co;2-thttps://research.rug.nl/en/publications/557afc4a-1188-4d20-86ea-47563bbaffbc