6533b7d5fe1ef96bd1264f8e
RESEARCH PRODUCT
N-benzoylindole-2,3-quinodimethane: Diels-Alder reactivity and synthetic applications for [b]annellated indoles
Ulf PindurManfred Habersubject
ChemistryOrganic ChemistryDrug DiscoveryDiels alderOrganic chemistryFrontier molecular orbital theoryReactivity (chemistry)BiochemistryCycloadditionQuinonedescription
Abstract The Diels-Alder reactivity of in situ generated N -benzoylindole-2,3-quinodimethane has been expanded considerably to include reactions with carbon- and hetero-dienophiles which furnish a variety of [ b ]annellated indoles as well as functionalized and annellated carbazoles. The frontier molecular orbital theory was found to be a useful model for the prediction of the experimental results under consideration of reactivity aspects.
year | journal | country | edition | language |
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1991-03-01 | Tetrahedron |