6533b7d5fe1ef96bd1265017

RESEARCH PRODUCT

Inside Front Cover: A Combined Top-Down/Bottom-Up Approach for the Nanoscale Patterning of Spin-Crossover Coordination Polymers (Adv. Mater. 16/2007)

Saioa CoboAzzedine BousseksouGábor MolnárEmmanuelle DaranFranck CarcenacChristophe VieuJosé Antonio Real

subject

chemistry.chemical_classificationMaterials scienceBistabilitybusiness.industryCoordination polymerScanning electron microscopeMechanical EngineeringSchematicNanotechnologyPolymerchemistry.chemical_compoundchemistryMechanics of MaterialsSpin crossoverOptoelectronicsGeneral Materials ScienceThin filmbusinessNanoscopic scale

description

The background scanning electron microscopy image shows nanometric patterns of the 3D spin crossover coordination polymer Fe(pyrazine)[Pt(CN)4] (see schematic structure in the circle), which have been fabricated using a combination of lift-off and multilayer sequential assembly methods. These patterns, reported by Gabor Molnar, Azzedine Bousseksou, and co-workers on p. 2163, exhibit a bistability of their electronic states (1A1 ⇌ 5T2), and thus represent a novel platform for a wide array of potential applications.

https://doi.org/10.1002/adma.200790060