6533b7d5fe1ef96bd1265039
RESEARCH PRODUCT
Metal complexes of sulfanilamide derivatives. Spectroscopic characterization of the dichloro disulfathiazole methanol copper(II) complex
J. CasanovaLeontin DavidGloria AlzuetJoaquín BorrásDante Gatteschisubject
Inorganic chemistrychemistry.chemical_elementCopperSquare pyramidal molecular geometrylaw.inventionInorganic ChemistryMetalTrigonal bipyramidal molecular geometryCrystallographychemistrylawvisual_artMaterials Chemistryvisual_art.visual_art_mediumMoleculeCrystallitePhysical and Theoretical ChemistryElectron paramagnetic resonanceSingle crystaldescription
The synthesis and spectral characterization of the [Cu(Hstz)2(MeOH)Cl2] complex are described. Both polycrystalline powder EPR and single crystal EPR spectra recorded at room temperature show rhombic distortion with values of g1=2.25, g2=2.09 and g3=2.03 in agreement with a copper polyhedron, intermediate between trigonal bipyramid and square pyramidal.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1993-09-01 | Inorganica Chimica Acta |