6533b7d5fe1ef96bd1265072
RESEARCH PRODUCT
Synthesis of Photoreactive Block Copolymers Based on 1-Iminopyridinium Ylides
Daniel KlingerDaniel KlingerPatrick TheatoPatrick Theatosubject
chemistry.chemical_classificationchemistry.chemical_compoundMonomerchemistryPolymerizationYlidePolymer chemistryRadical polymerizationAlkoxy groupCopolymerChain transferGeneral ChemistryPyridiniumdescription
Two photoreactive pyridinium ylide containing monomers, {[2-(metacryloyloxy)ethoxy]carbonyl}(pyridinium-1-yl)azanide (M1) and pyridinium-1-yl-(4-vinylbenzoyl)azanide (M2), were synthesized. Both monomers were polymerized under controlled radical polymerization conditions, i.e. reversible addition–fragmentation chain transfer polymerization (M1 and M2) and nitroxide-mediated polymerization (M2). Further block copolymers PMMA-b-PM1 and PS-b-PM2 were successfully synthesized and their molecular weight, Mn, and block ratio could be determined by 1H NMR analysis, thereby opening the synthetic possibilities of photoreactive ylides in block copolymer syntheses.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-01-01 | Australian Journal of Chemistry |