6533b7d5fe1ef96bd12650f7

RESEARCH PRODUCT

Bis(5-tert-butyl-2-hydroxy-3-methylbenzyl)(6-hydroxyhexyl)ammonium chloride monohydrate, an anion receptor complex

Harri SopoReijo Sillanpää

subject

AnionsModels Molecularinorganic chemicalsBenzylaminesStereochemistryChemistryHydrogen bondIntermolecular forceHydrogen BondingGeneral MedicineCrystallography X-RayChlorideMedicinal chemistryAmmonium ChlorideGeneral Biochemistry Genetics and Molecular BiologyIonchemistry.chemical_compoundIntramolecular forcemedicineMoleculePhenolAmmonium chloridemedicine.drug

description

In the title compound, C(30)H(48)NO(3)(+) x Cl(-) x H(2)O, the cation acts with a water molecule as a chloride ion receptor. The chloride ion forms three strong intramolecular hydrogen bonds. The water molecule forms both an intramolecular bridge between one phenol H atom and the chloride ion, and an intermolecular link to the aliphatic alcohol O atom. Weak intermolecular C-H...Cl and C-H ...O hydrogen bonds provide additional packing interactions.

yearjournalcountryeditionlanguage
2007-06-14Acta Crystallographica Section C Crystal Structure Communications
https://doi.org/10.1107/s0108270107023797