6533b7d6fe1ef96bd1265a75
RESEARCH PRODUCT
Acene-type donors bearing one 1,3-dithiole ring
Rafael ViruelaEnrique OrtíLuis SánchezNazario Martínsubject
Bearing (mechanical)StereochemistryChemistryMechanical EngineeringMetals and AlloysElectron donorCondensed Matter PhysicsRing (chemistry)Chemical synthesisPhosphonateMedicinal chemistryElectronic Optical and Magnetic Materialslaw.inventionchemistry.chemical_compoundMechanics of MaterialslawMaterials ChemistryMoleculeAceneUnit (ring theory)description
Abstract A series of acene-type donors bearing only one 1,3-dithiole ring have been synthesized by following a Wittig-Horner reaction from 7 H -benz[ d,e ]anthracen-7-one and several phosphonate esters. The excellent donor properties have been studied using both experimental techniques and quantum-chemical calculations and reveal that the extraction of the first electron in the oxidation process occurs from the dithiole ring (0.42 e) and the acene unit (0.58 e).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-06-01 | Synthetic Metals |