6533b7d6fe1ef96bd1265c81

RESEARCH PRODUCT

Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons.

Filip TopićFilip TopićTomislav FriščićKatarina LisacKatarina LisacMihails ArhangelskisKari RissanenDominik Cinčić

subject

inorganic chemicalsHydrogenchemistry.chemical_element010402 general chemistry01 natural sciencesCocrystalCatalysiskemialliset sidoksetOrthogonalityTrimorphismMaterials Chemistrysupramolekulaarinen kemiavetysidokset010405 organic chemistryHydrogen bondSynthonMetals and Alloysorthogonality halogen bond hydrogen bond cocrystal trimorphismGeneral Chemistrykiteet0104 chemical sciences3. Good healthSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistryHalogenCeramics and Composites

description

True trimorphic cocrystals, i.e. multi-component molecular crystals of identical composition that exhibit three polymorphic structures, are exceedingly rare and so far no halogen-bonded cocrystal system has been reported to exhibit trimorphism. Here we describe a unique example of a trimorphic cocrystal exhibiting both hydrogen and halogen bonds in which the differences between polymorphs reveal their orthogonality, evident by the apparently independent variation of well-defined hydrogen- and halogen-bonded motifs. peerReviewed

yearjournalcountryeditionlanguage
2019-11-07Chemical communications (Cambridge, England)
10.1039/c9cc06735chttps://pubmed.ncbi.nlm.nih.gov/31693025