6533b7d6fe1ef96bd1265d30

RESEARCH PRODUCT

On the Lindemann criterion for quantum clusters at very low temperature.

J. NavarroR. Guardiola

subject

PhysicsQuantum mechanicsCluster (physics)SymmetrizationDiffusion Monte CarloPhysical and Theoretical ChemistryWave functionQuantumSymmetry (physics)Identical particlesBoson

description

The Lindemann criterion to discern the solid-like or liquid-like nature of a quantum cluster at T = 0 is discussed. A critical analysis of current Lindemann parameters is presented and a new parameter is proposed that is appropriate to study quantum clusters made of identical particles. A simple model wave function is introduced to fix the range of variation of these parameters. The model presents two extreme limits that correspond to either a liquid-like or a solid-like system; besides, it fulfills the Bose symmetry and also permits evaluations without symmetrization. Variational and diffusion Monte Carlo calculations are also performed for clusters of spinless bosons interacting through Lennard-Jones potentials. It is shown that the liquid-like or solid-like character of quantum clusters at zero temperature cannot be simply established in terms of a single parameter.

10.1021/jp1111313https://pubmed.ncbi.nlm.nih.gov/21341740