6533b7d6fe1ef96bd12667bd

RESEARCH PRODUCT

Crystal structure and Hirshfeld surface analysis of (E)-3-(benzylideneamino)-5-phenylthiazolidin-2-iminium bromide

Abel M. MaharramovGulnara Sh. DuruskariGunay Z. MammadovaMehmet AkkurtTaras Chyrka

subject

chemistry.chemical_classificationcrystal structureCrystallographyHydrogen bondIminiumSalt (chemistry)General ChemistryCrystal structureCondensed Matter::Mesoscopic Systems and Quantum Hall EffectCondensed Matter PhysicsRing (chemistry)Crystalchemistry.chemical_compoundCrystallographychemistryBromideQD901-999Atomcharge assisted hydrogen bondinghirshfeld surface analysisthiazolidine ringenvelope conformationGeneral Materials Science

description

The central thiazolidine ring of the title salt, C16H16N3S+center dot Br-, adopts an envelope conformation, with the C atom bearing the phenyl ring as the flap atom. In the crystal, the cations and anions are linked by N-H center dot center dot center dot Br hydrogen bonds, forming chains parallel to the b-axis direction. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H center dot center dot center dot H (46.4%), C center dot center dot center dot H/H center dot center dot center dot C (18.6%) and H center dot center dot center dot Br/Br center dot center dot center dot H (17.5%) interactions.

yearjournalcountryeditionlanguage
2020-02-21Acta Crystallographica Section E: Crystallographic Communications
10.1107/s2056989020001899http://scripts.iucr.org/cgi-bin/paper?S2056989020001899