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RESEARCH PRODUCT
Block Copolymers Build-up of Electron and Hole Transport Materials
Marc BehlRudolf Zentelsubject
chemistry.chemical_classificationMaterials sciencePolymers and PlasticsOrganic ChemistryDispersityRadical polymerizationPolymerCondensed Matter Physicschemistry.chemical_compoundMonomerchemistryPolymerizationPhase (matter)Polymer chemistryMaterials ChemistryCopolymerLiving polymerizationPhysical and Theoretical Chemistrydescription
In this article we describe the synthesis of various monomers modified with triphenyl-1,3,5-triazine side groups as electron transport moieties. By nitroxide-mediated polymerization with a TEMPO unimer it was possible to obtain polymers with a narrow polydispersity. Furthermore, by living radical polymerization block copolymers were obtained from these monomers. Therefore, microphase separated structures are accessible which possess hole conducting moieties in one phase and electron conducting moieties in the other phase.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-08-12 | Macromolecular Chemistry and Physics |