Der austausch des cyclopentadienylliganden im methylcyclopentadienyl-mangantricarbonyl

6533b7d6fe1ef96bd1266f6d

RESEARCH PRODUCT

Der austausch des cyclopentadienylliganden im methylcyclopentadienyl-mangantricarbonyl

Paul Bachmann Josef Lösch Hans Werner Furk Hellmut Singer

subject

Organic Chemistry Halide chemistry.chemical_element Ring (chemistry)Biochemistry Medicinal chemistry Decomposition Toluene Inorganic Chemistry chemistry.chemical_compound Cyclopentadienyl complex chemistry Aluminium Yield (chemistry)Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Benzene

description

Abstract The exchange of the cyclopentadienyl ring in methylcyclopentadienylmanganese(I) tricarbonyl by methy-substituted benzenes in the presence of aluminium halide leads to [arene-Mn(CO) 3 ] + -ions. The reaction conditions have been optimised; in addition to the yield the purity of the complexes has been determined in some detail. After mild decomposition the arenes were analysed by GLC. Pure [arene-Mn(CO) 3 ] + -ions can be isolated with benzene, toluene, m - and o -xylene.

year	journal	country	edition	language
1981-06-01	Journal of Organometallic Chemistry

https://doi.org/10.1016/s0022-328x(00)81921-x

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