Search results for "Aluminium"
showing 10 items of 548 documents
Defects in yttrium aluminium perovskite and garnet crystals: atomistic study
2000
Native and impurity point defects in both yttrium aluminium perovskite (YAP) and garnet (YAG) crystals are studied in the framework of the pair-potential approximation coupled with the shell model description of the lattice ions. The calculated formation energies for native defects suggest that the antisite disorder is preferred over the Frenkel and Schottky-like disorder in both YAP and YAG. The calculated values of the distortion caused by the antisite YAl x in the lattice turn out to be in an excellent agreement with the EXAFS measurements. In non-stoichiometric compounds, the calculated reaction energies indicate that excess Y2 O3 or Al2 O3 is most likely to be accommodated by the forma…
Mechanism of anionic polymerization of methyl methacrylate in the presence of aluminium alkyls
1995
Methyl methacrylate was polymerized with tert-butyl lithium in the presence of triethylaluminium or triisobutylaluminium at 78°C in toluene. As indicated by GPC and MALDI-TOF mass spectrometry, the polymerization is accompanied by side reactions. The lower oligomers were fractionated by distillation and characterised by NMR, FT-IR, UV and electron impact (EI) mass spectrometry. All these data show that part of the polymer chains are carrying exactly one tert-butyl isoprenyl ketone unit. In order to avoid the formation of tert-butyl isoprenyl ketone a molar ratio of Al/Li>2 is necessary.
Effect of high temperature annealing (T > 1650 °C) on the morphological and electrical properties of p-type implanted 4H-SiC layers
2019
This work reports on the effect of high temperature annealing on the electrical properties of p-type implanted 4H-SiC. Ion implantations of Aluminum (Al) at different energies (30-200 keV) were carried out to achieve 300 nm thick acceptor box profiles with a concentration of about 10(20) at/cm(3). The implanted samples were annealed at high temperatures (1675-1825 degrees C). Morphological analyses of the annealed samples revealed only a slight increase of the surface roughness RMS up to 1775 degrees C, while this increase becomes more significant at 1825 degrees C (RMS = 1.2 nm). Room temperature Hall measurements resulted in a hole concentration in the range 0.65-1.34 x 10(18)/cm(3) and m…
Low-temperature Ti-containing 3:2 and 2:1 mullite nanocrystals from single-phase gels
2007
Abstract TiO 2 -containig single-phase gels with (Al 2 O 3 + TiO 2 )/(SiO 2 ) molar ratios 3/2 and 2/1 were prepared by gelling mixtures of aluminium nitrate, tetraethylorthosilicate and titanium isopropoxide. Gels were fast heated at several temperatures up to 1100 °C. Dried and heated gels were characterized by differential thermal analysis (DTA), magic angle spinning nuclear magnetic resonance (MAS-NMR), X-ray powder diffraction (XRD), and scanning and transmission electron microscopies (SEM and TEM). Coupled DTA and XRD results of gels fast heated at 900 °C showed the crystallisation of two mullites as well as a small amount of alumina-silica spinel. 27 Al NMR spectra showed the format…
On the Measurement and Prediction of the Out-of-Plane Displacement Surrounding Cold-Expanded Holes
2010
Experimental measurements of the out-of-plane displacement surrounding cold-expanded holes in a 6082-T6 aluminum alloy were made with a 3D optical scanner using the technique of the encoded light-pattern projection in white light. The measured surface profiles have shown the thickness discontinuity along the hole edge due to the effect of the split in the sleeve. An analytical–numerical solution of the out-of-plane displacement is presented based on existing analytical models. Thus, the results given by the analytical model were then compared with the experimental data and with a finite element (FE) model that simulates the cold-expansion process. The location of the elastic–plastic boundar…
Optical Properties of Monolayer-Protected Aluminum Clusters: Time-Dependent Density Functional Theory Study
2015
We examine the electronic and optical properties of experimentally known monolayer-protected aluminum clusters Al4(C5H5)4, Al50(C5Me5)12, and Al69(N(SiMe3)2)183– using time-dependent density functional theory. By comparing Al4(C5H5)4 and the theoretical Al4(N(SiMe3)2)4 cluster, we observe significant changes in the optical absorption spectra caused by different hybridization between metal core and ligands. Using these initial observations, we explain the calculated spectra of Al50(C5Me5)12 and Al69(N(SiMe3)2)183–. Al50(C5Me5)12 shows a structured spectrum with clear regions of low-intensity core-to-core transitions followed by high-intensity ligand-to-core transitions due to its high symmet…
Droplet cell investigation of intergranular corrosion on AA2024
2017
An original method combining a droplet cell with direct optical interrogation of the reverse side of a 50μm thick foil AA2024 has been tested to evaluate the possible analysis of the current during intergranular corrosion tests. The foil microstructure and the selected orientation were suitable for recording the current generated during the propagation in volume of a well-defined grain boundary trace. Even if it is impossible to reach a charge and mass balance from these preliminary attempts, it was demonstrated that it is possible, despite hydrogen evolution, to record a current transient resulting from the full penetration of an intergranular path. Keywords: Intergranular corrosion, Alumi…
Experimental Comparison of the MIG and Friction Stir Welding Processes for AA 6005 Aluminium Alloy
2015
In this study, the mechanical properties of welded joints of AA 6005 aluminum alloy obtained with friction stir welding (FSW) and conventional metal inert gas welding (MIG) are studied. FSW welds were carried out on a semi-automatic milling machine. The performance of FSW and MIG welded joints were identified using tensile and bending impact tests, as far as the environmental aspects are also included in the discussion. The joints obtained with FSW and MIG processes were also investigated in their microstructure. The results indicate that, the microstructure of the friction stir weld is different from that of MIG welded joint. The weld nugget consists of small grains in FSW than those found…
Process Mechanics in Friction Stir Welding of Magnesium Alloys: Experimental and Numerical Analysis
2012
Light weight construction is a major task within automotive and aircraft industry due to lower fuel consumption or increase the possible payload. Structural or exterior shell components are more and more manufactured out of aluminum alloys for this reason. A further weight reduction could be achieved by the substitution of aluminum alloys by magnesium alloys. Also the application of blanks with a varying thickness is a possibility to realize light weight design. To combine the advantages of weight reduction by the use of magnesium alloys and tailored welded blanks (TWBs), an effective joining technique is required. Friction Stir Welding can be used for difficult to be welded magnesium alloy…
A Comparative Analysis of the Machined Surfaces Quality of an Aluminum Alloy According to the Cutting Speed and Cutting Depth Variations
2019
The milling operations are a topical and especially future-oriented methods. The purpose of this scientific paper is to carry out an experimental research referring to the end-milling process of the 7136 aluminum alloy. This paper is a continuation of the own research activity carried out so far, within a company with the field of activity in the aerospace industry. The main objective is a comparative analysis which was carried out on the surface quality - machined on various cutting regimes. The cutting process parameters used in the end-milling process are: the cutting speed, the feed per tooth and the cutting depth. The obtained results of the surface roughness’s were measured longitudin…